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[DOI] [PMC free article] [PubMed] [Google Scholar] 70.Xu W, Huang Y, Zhou R

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Reoxidation of adduction products can allow multiple adduction events to take place.(542) The reaction of 1,2-quinones with amine functions is 10 5 -fold slower than adduction to thiols.(543) Selenocysteine [Sec, p K a 5.2(544)] is a genetically encoded analog of cysteine that is present in around 25 proteins in humans.(545) Although the precise reasons for incorporation of Sec into proteins is debated,(546,547) it is clear that Sec is intrinsically more nucleophilic than cysteine.(548) Unsurprisingly, Sec is a target of both ROS and RES