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For example, irradiation (250 W lamp) of an oxygen-purged solution of LA in methanol containing 0.05% methylene blue at 5 °C produces a mixture of 9( R,S )- and 13( R,S )-HpODEs as well as 10( R,S )-HpODE 3 and 12( R,S )-HpODE 4 (Scheme 54)

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Chemotherapy triggers HIF-1–dependent glutathione synthesis and copper chelation that induces the breast cancer stem cell phenotype